Les spectres de masse dans l' analyse 10e communication [1] les transferts d'hygrogène dans des cétones norbornyliques
- 20 April 1967
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 50 (3) , 826-840
- https://doi.org/10.1002/hlca.19670500310
Abstract
Some simple rules for predicting the transfer of endo hydrogens in the mass spectra of norbornane carbonyl derivatives are proposed. Transfers from C‐6 to C‐2 generally occur, but are repressed if a methyl group is on C‐1. Transfers from C‐5 to C‐2 can occur, but are less favorable than 1‐3 transfers. Endo‐2‐acetylnorbornanes undergo a γ‐hydrogen transfer from C‐5 with ring fission.Keywords
This publication has 35 references indexed in Scilit:
- Relative Rates of Base-Catalyzed Enolization of 2-Butanone1,2Journal of the American Chemical Society, 1966
- A Mass Spectral Study of exo- and endo-2-Norbornyl Bromides1Journal of the American Chemical Society, 1966
- Mass Spectrometry in Structural and Stereochemical Problems. XCIII.1 Further Observations on the Importance of Interatomic Distance in the McLafferty Rearrangement. Synthesis and Fragmentation Behavior of Deuterium-Labeled 12-Keto Steroids2,3Journal of the American Chemical Society, 1966
- Substituent Effects in Unimolecular Ion Decompositions. II. A Linear Free Energy Relationship between Acyl Ion Intensities in the Mass Spectra of Substituted Acylbenzenes1,2Journal of the American Chemical Society, 1966
- The Nitrous Acid Deamination of the Norbornylamines. Carbon and Nitrogen Rearrangements of Norbornyl CationsJournal of the American Chemical Society, 1964
- Analysis of the Nuclear, Magnetic Resonance Spectra of Norbornene DerivativesJournal of the American Chemical Society, 1964
- THE CHROMIC ACID OXIDATION OF ORGANOBORANES—A CONVENIENT PROCEDURE FOR CONVERTING OLEFINS INTO KETONES via HYDROBORATIONJournal of the American Chemical Society, 1961
- The Stereochemistry of the Perbenzoic Acid Oxidation of Optically Active exo-Acetylnorbornane1Journal of the American Chemical Society, 1959
- Photochemical Reactions. VII.1 The Intramolecular Cyclization of Carvone to Carvonecamphor2Journal of the American Chemical Society, 1957
- The Configuration of Isocamphenilanol1Journal of the American Chemical Society, 1952