Lower Bounds for the Helmholtz Function
- 22 February 1965
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 137 (4B) , B1127-B1128
- https://doi.org/10.1103/physrev.137.b1127
Abstract
A mathematical theorem is established for traces of products of bounded Hermitian and definite operators, a and b: for a non-negative integer. This theorem is applied to the equilibrium partition function by exploiting an infinite-product representation of the exponential function of the sum of two operators. As a result, a set of inequalities is established which yields a set of upper bounds for the partition function. This result is invariant to the particle statistics of the system. A general argument yields the result that the classical Helmholtz free-energy function serves as a lower bound to the corresponding quantum result.
Keywords
This publication has 4 references indexed in Scilit:
- Gibbs' Third Variational Principle in Statistical ThermodynamicsThe Journal of Chemical Physics, 1964
- Variational Method for Classical Statistical MechanicsThe Journal of Chemical Physics, 1964
- Statistical Theory of Many-Electron Systems. Discrete Bases of RepresentationPhysical Review B, 1957
- Partition Function for a System of Interacting Bose-Einstein ParticlesPhysical Review B, 1955