Chemistry of η5-fullerene metal complexes
- 1 January 2001
- journal article
- Published by Walter de Gruyter GmbH in Pure and Applied Chemistry
- Vol. 73 (2) , 355-359
- https://doi.org/10.1351/pac200173020355
Abstract
Treatment of [60]fullerene with an organocopper reagent converts one of the pentagons of the fullerene into cyclopentadienyl anion through addition of five organic groups on every peripheral carbon atom surrounding the pentagon. Similar treatment of [70]fullerene afforded indenyl anion through regioselective tri-addition of the organic group. These anionic moieties strongly interact with the remainder of the fullerene p-system, and provide unique opportunity for exploration of organometallic chemistry of a new class of metal cyclopentadienides.Keywords
This publication has 1 reference indexed in Scilit:
- A Cage with Fullerene End CapsJournal of the American Chemical Society, 2000