RHODIUM CARBONYL CLUSTER CATALYZED ADDITION OF ARENES TO DIPHENYLKETENE AND ARYL ISOCYANATES

Abstract
Under pressure of carbon monoxide, rhodium carbonyl clusters catalyze a novel addition of benzene and monosubstituted benzenes to diphenylketene and aryl isocyanates to give benzene-adducts, diphenylmethyl arylketone and N-aryl benzamides, respectively.

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