Cleavage of cyclopropane rings with rhodium(I) octaethylporphyrin anion
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 572-573
- https://doi.org/10.1039/c39750000572
Abstract
Reactions of rhodium(I) octaethylporphyrin ion with cyclopropanes substituted with an electron-with-drawing group and with highly strained cyclopropane derivatives such as quadricyclane gave alkylrhodium(III) octaethylporphyrin complexes resulting from C–C bond cleavage of the cyclopropane ring.Keywords
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