Electronic and mechanical properties of carbon nitride films prepared by laser ablation graphite under nitrogen ion beam bombardment
- 12 September 1994
- journal article
- Published by AIP Publishing in Applied Physics Letters
- Vol. 65 (11) , 1361-1363
- https://doi.org/10.1063/1.112052
Abstract
Carbon nitride films have been formed on Si(100) substrates by laser ablation of graphite under a low energy nitrogen ion beam bombardment. Data of Raman shift and x-ray photoelectron spectroscopy indicate the existence of carbon-nitrogen bonds in the films. Time-of-flight measurements suggest the existence of paracyanogen-like materials, such as C4N4, in the films. High energy backscattering spectrometry has shown that the percentage of N content in the film is 41% or so. The x-ray diffraction and transmission electron micrograph measurements have also been taken to characterize the crystal properties of the obtained films. Qualitative tests indicate the films of high Vickers hardness Hv, and of good adhesion to the silicon substrates.Keywords
This publication has 11 references indexed in Scilit:
- Predicting Useful MaterialsScience, 1993
- Analytical electron microscopy and Raman spectroscopy studies of carbon nitride thin filmsJournal of Vacuum Science & Technology A, 1993
- Carbon–Nitrogen Pyrolyzates: Attempted Preparation of Carbon NitrideJournal of the American Ceramic Society, 1991
- A graphitic carbon nitrideJournal of Materials Science Letters, 1990
- Structure and bonding studies of the C:N thin films produced by rf sputtering methodJournal of Materials Research, 1990
- Chemical Preparation and Shock Wave Compression of Carbon Nitride PrecursorsJournal of the American Ceramic Society, 1990
- Prediction of New Low Compressibility SolidsScience, 1989
- Structural and optical properties of amorphous carbon nitrideSolid State Communications, 1988
- Calculation of bulk moduli of diamond and zinc-blende solidsPhysical Review B, 1985
- Reactive sputtering of carbon and carbide targets in nitrogenJournal of Vacuum Science and Technology, 1979