New palladium cluster compounds. X-Ray crystal structure of Pd10(CO)12(PBu3 n)6
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 989-990
- https://doi.org/10.1039/c39810000989
Abstract
The ten-vertex palladium cluster Pd10(CO)12[PBun 3]6 obtained by treatment of Pd(OAc)2 with PBun 3 and CO [molar ratio Pd : P 1 : 4·5], is shown by X-ray crystallography to contain a tetracapped octahedron of metal atoms, i.e. a distorted fragment of close packing Pd10 with 16 skeletal electrons.Keywords
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