[HRu6(CO)18]–: a ruthenium anion having an interstitial H-ligand. X-Ray crystal structures of two modifications
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 945-946
- https://doi.org/10.1039/c39760000945
Abstract
Reaction of [Ru3(CO)12] with [Mn(CO)5]– gives [Ru6(CO)18]2– which on acidification is converted into [HRu6(CO)18]–; this monoanion has spectroscopic properties and an X-ray structure consistent with the H ligand lying at the centre of an octahedron (approximating to Oh symmetry) of ruthenium atoms.Keywords
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