Identification of Some Global Volcanic Horizons by Major Element Analysis of Fine Ash in Antarctic Ice

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Abstract
Acid fallout from volcanic eruptions is well documented in the Greenland and Antarctic ice sheets (Hammer and others, 1980; Hammer, 1984; Legrand and Delmas, 1987). However, to date, no volcanic ash (tephra) layers have been positively identified in association with any of the high electrical conductivity layers that mark the volcanic acid deposition. In this paper we report the results of a study of the chemical composition of insoluble microparticles filtered from five intervals of a core from the South Pole. These five intervals were identified by Kirchner (1988) as being due to volcanic fallout, on the basis of electrical conductivity and sulfuric acid measurements.The major element composition of tiny (µm) glass shards found in these layers was determined and compared with analyses of volcanic ash from known eruptions or from volcanic sources suspected of having produced the fallout. Glass shards from volcanic eruptions of both local (Antarctic and sub-Antarctic) and of global (Indonesian/South American) importance have been identified in this study.