Formation of an η2-formaldehyde compound from methanol and its hydrogenation giving methanol
- 1 January 1984
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1540
- https://doi.org/10.1039/c39840001540
Abstract
Addition of methanol to W(PMe3)4(η2-CH2PMe2)H gives the η2-formaldehyde derivative W(PMe3)4(η2-CH2O)H2 which reacts sequentially with dihydrogen forming initially the methoxyhydrido compound W(PMe3)4(OMe)H3 and then W(PMe3)4H4 accompanied by the production of MeOH.Keywords
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