Metal-catalysed addition of β-dicarbony compounds to the nitrile carbon of benzoyl cyanide. Synthesis of 1-amino-1-benzoyl-2,2-diacylethenes
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 23,p. 1593-1594
- https://doi.org/10.1039/c39840001593
Abstract
The complex [Ni(acac)2](Hacac pentane-2,4-dione) selectively catalyses addition of the intercarbonylic carbon atom of β-diketones to the cyano group of benzoyl cyanide, whereas usual basic organic catalysts lead to attack on the carbonyl carbon atom with displacement of the CN group.Keywords
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