Crystal and molecular structure of potassium bis(dimethylphenylphosphine)bis(dithiocarbonato)rhodate(III) trihydrate
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 17,p. 1713-1715
- https://doi.org/10.1039/dt9760001713
Abstract
The structure of the title compound (II), K[Rh(S2CO)2(PMe2Ph)2]·3H2O has been determined. Crystals are monoclinic, space group P21/c, with a= 18.798, b= 6.516, c= 23.924 Å, β= 113.91°. There are two independent anions per unit cell with crystallographic Ci() symmetry. They are essentially identical, and the planar dithiocarbonate ligands have Rh–S 2.37, C–S 1.725, C–O 1.25 Å; S–Rh–S 73.5, S–C–S 111, and S–C–O 125°.Keywords
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