Polynuclear cyclometallated palladium (II) complexes derived from potentially hexadentate Schiff base ligands. Crystal structures of [(Cl)Pd{Me2NCH2CH2N(H)C}C6H2{C(H)NCH2CH2NMe2}Pd(Cl)] and [{(Ph2PCH2CH2)2PPh-P,P,P}Pd{Me2NCH2CH2N(H)C}C6H2{C(H)NCH2CH2NMe2}Pd{(Ph2PCH2CH2)2PPh-P,P,P}][Cl]2
- 20 October 2000
- journal article
- Published by Elsevier in Journal of Organometallic Chemistry
- Vol. 612 (1-2) , 85-95
- https://doi.org/10.1016/s0022-328x(00)00417-4
Abstract
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This publication has 64 references indexed in Scilit:
- Cyclometalated Complexes with Triphosphine Ligands: A Novel Route for Promoting Pentacoordination in Palladium(II)Organometallics, 1999
- Cyclometalated Compounds. XI.1 Single and Double Cyclometalations of Poly(pyrazolylmethyl)benzenesOrganometallics, 1998
- Stereoselectivity in Organometallic Reactions: Intramolecular Oxidative Addition of Aryl−Halogen Bonds to Platinum(II)Organometallics, 1998
- Synthesis of Mercury(II) and Palladium(II) Organometallic Derivatives of Terephthaldehyde by Metalation, Transmetalation, Oxidation, and Condensation Reactions. X-ray Crystal Structures of trans-[PdCl{C6H3(CO2H)2-2,5}(PPh3)2]·Me2CO·2MeOH, trans-[PdCl{C6H3(CHO)-2-(CO2H)-5}(PPh3)2]·2CH2Cl2, and [Pd{C6H3(CHNC6H4NH2-4)-2-(CHO)-5}(N,N,N‘,N‘-Tetramethylethylenediamine)]CF3SO3. Molecular Assemblies through [Pd]−Cl···HO2C−Aryl and [Pd]−Cl···HOMe HO(O)C−Aryl Hydrogen Bonds†Organometallics, 1997
- Preparation and Properties oftrans-Pd(Ar)(C⋮CPh)(PEt3)2. Intermolecular Alkynyl Ligand Transfer between Copper(I) and Palladium(II) Complexes Relevant to Palladium Complex Catalyzed Cross-Coupling of Terminal Alkyne with Haloarene in the Presence of CuI CocatalystOrganometallics, 1997
- Rigid five- and six-membered C,N,N'-bound aryl-, benzyl-, and alkylorganopalladium complexes: sp2 vs. sp3 carbon-hydrogen activation during cyclopalladation and palladium(IV) intermediates in oxidative addition reactions with dihalogens and alkyl halidesOrganometallics, 1993
- Insertion of alkynes into the palladium-carbon bond of palladacycles. Mechanistic information from high-pressure kinetic and x-ray structural dataOrganometallics, 1993
- Synthesis and reactions of cyclopalladated compounds derived from N,N′-dialkylbenzene-1,3-dicarbaldimines [alkyl = ethyl (H2L1), butyl or octyl] and N,N′-dibenzylbenzene-1,3-dicarbaldimine. Crystal structure of [Pd2L1(py)4][ClO4]2(py = pyridine)J. Chem. Soc., Dalton Trans., 1991
- Reactivity of dimetallated benzalazinesTransition Metal Chemistry, 1984
- Aromatic Metalation Reactions by Palladium(II) and Platinum(II) on Aromatic Aldoximes and KetoximesBulletin of the Chemical Society of Japan, 1970