Ionization and dissociation of cyclic ethers and thioethers by electron‐impact. A comparison between 1,4 dioxane, 1,4 dithiane and 1,4 oxathiane
- 1 December 1969
- journal article
- research article
- Published by Wiley in Journal of Mass Spectrometry
- Vol. 2 (12) , 1277-1287
- https://doi.org/10.1002/oms.1210021209
Abstract
The various modes of fragmentation of 1,4 dithiane and 1,4 oxathiane under electron‐impact have been discussed using variation of their mass spectra with electrons energy, high resolution and AP of the main ions. It is shown that they are qualitatively very similar, but differ considerably from those of 1,4 dioxane.Keywords
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