The first X-ray structurally characterized M3L2 cage-like complex with tetrahedral metal centres and its encapsulation of a neutral guest molecule
- 21 March 2000
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 591-592
- https://doi.org/10.1039/b000259n
Abstract
The first X-ray structurally characterized M3L2 cage-like complex with tetrahedral metal centres [Zn3(tib)2- (OAc)6]·xH2O [tib = 1,3,5-tris(imidazol-1-ylmethyl)benzene, x ≈ 4] obtained by reaction of zinc(II) acetate with the tripodal ligand tib exhibits guest inclusion properties of neutral molecule such as synthetic camphor in aqueous solution.Keywords
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