Kinetic resolution of chiral aminoalkenes via asymmetric hydroamination/cyclisation using binaphtholate yttrium complexesElectronic supplementary information (ESI) available: experimental procedures and characterising data for all new complexes and substrates. See http://www.rsc.org/suppdata/cc/b3/b316096c/
- 20 February 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 6,p. 730-731
- https://doi.org/10.1039/b316096c
Abstract
Chiral binaphtholate yttrium aryl complexes are highly active and enantioselective catalysts for the asymmetric hydroamination of aminoalkenes, as well as the kinetic resolution of α-substituted 1-aminopent-4-enes to give trans-2,5-disubstituted pyrrolidines with good enantiomeric excess and high krel.Keywords
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