C3-Symmetrical lanthanide podates organized by intramolecular trifurcated hydrogen bonds
- 1 January 1999
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 5,p. 457-458
- https://doi.org/10.1039/a809742i
Abstract
The protonated tripodal podand [L6 + H]+ forms stable and organized monometallic podates [Ln(L6 + H)]4+ where LnIII is facially nine-coordinated by three wrapped unsymmetrical tridentate binding units. An unusual trifurcated hydrogen bond assists the organisation of the covalent tripod.Keywords
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