The vibrational spectra of the halides and complex halides of arsenic(III). Part I. Liquid and solid arsenic trichloride and arsenic tribromide, and their solutions in tri-n-butyl phosphate
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1757-1760
- https://doi.org/10.1039/j19680001757
Abstract
The infrared and Raman spectra of solutions of arsenic trichloride and arsenic tribromide in tri-n-butyl phosphate (TBP) are reported and interpreted in terms of formation of 1 : 2 complexes, AsCl3,2TBP and AsBr3,2TBP. The Raman spectra of arsenic trichloride and arsenic tribromide in the liquid and solid states are also reported and discussed, particularly in relation to earlier spectroscopic studies.Keywords
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