$K$ -edge x-ray absorption spectra in an octahedral environment. A theoretical and experimental study of Mo ${(CO)}_{6}$

1 November 1982

journal article
research article
Published by American Physical Society (APS) in Physical Review A

Vol. 26 (5) , 3020-3022
https://doi.org/10.1103/physreva.26.3020

Abstract

We report measurements of the

K

-edge photoabsorption spectrum of the octahedral complex Mo

{(CO)}_{6}

and a theoretical calculation of this spectrum using the self-consistent-field

X α

multiple-scattered-wave approach. Two strong absorption peaks near threshold are shown to lie in the continuum region of the spectrum and to be of "shape resonance" character.

Keywords

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K-edge x-ray absorption spectra in an octahedral environment. A theoretical and experimental study of Mo(CO)6

Abstract

Keywords

$K$ -edge x-ray absorption spectra in an octahedral environment. A theoretical and experimental study of Mo ${(CO)}_{6}$