Diastereocontrol of thio-Claisen rearrangement induced by an adjacent hydroxy-substituted chiral centre
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 414-416
- https://doi.org/10.1039/c39890000414
Abstract
S-Allyl α-hydroxy ketene dithioacetals smoothly rearrange into α-allyl β-hydroxydithioesters with a high level of syn-diastereoselectivity, with the syn : anti ratio ranging from 24:1 to 6:1, independently of the geometry of the ketene double bond.Keywords
This publication has 0 references indexed in Scilit: