The Reactions of Complexes of Thioboronite with Compounds Containing Carbon-Nitrogen Multiple Bond

Abstract
n-Butyl di-n-butylthioboronite reacts with isocyanates to give 1:2 adducts, and with isothiocyanate or carbodiimide to give a 1:1 adduct. It was found that thioboronite forms a 1:1 co-ordinated complex with benzyl cyanide, and that the complex reacts with isocyanates to give the corresponding acetamidine derivatives in good yields.

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