Biogenetic Model Reactions of Epoxygermacrones
- 1 November 1976
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 49 (11) , 3137-3144
- https://doi.org/10.1246/bcsj.49.3137
Abstract
From a biogenetic point of view, acid- or base-catalyzed cyclizations of epoxygermacrones (2, 23, and 33) were carried out. In most cases, the stereospecific cyclizations of these epoxygermacrones took place to give many compounds with an 11-oxabicyclo[5.3.1]undecane system, cadinane-type, selinane-type or guaiane-type compounds depending on the kinds of reagents and solvents. The formation process of each cyclization product will be discussed in detail.Keywords
This publication has 2 references indexed in Scilit:
- Regio- and Stereospecific Cyclizations of GermacronesBulletin of the Chemical Society of Japan, 1976
- Sesquiterpenes from Acorus calamus L.Bulletin of the Chemical Society of Japan, 1975