An improved modified Poisson–Boltzmann equation in electric-double-layer theory
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 79 (5) , 707-718
- https://doi.org/10.1039/f29837900707
Abstract
A more accurate fluctuation potential problem is considered in the modified Poisson–Boltzmann theory. Numerical solutions of the resulting new equation are compared with those of the previous theory and 1 : 1, 1 : 2, 2 : 2 Monte Carlo calculations. The new modified Poisson–Boltzmann equation is found to be much more successful in predicting the Monte Carlo results, especially for the higher-valency electrolytes.Keywords
This publication has 0 references indexed in Scilit: