Excess volume and viscosity of binary liquid acid–base mixtures
- 15 October 1976
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 54 (20) , 3125-3129
- https://doi.org/10.1139/v76-446
Abstract
Densities, viscosities, and refractive indices at 25 °C were determined for the systems: o chlorophenol + N,N-dimethylaniline, o-chlorophenol + aniline, o-chlorophenol + m-toluidine, and o-chlorophenol + pyridine. From the experimental results the excess volume, excess viscosity, excess molar free energy of activation of flow, and the excess partial molar volume were calculated. There is evidence of complex formation between o-chlorophenol and the four bases.Keywords
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