Synthesis of homo and hetero palladium–platinum bimetallic complexes; X-ray crystal structure of Pt2Cl2(µ-CO)(PPh3)3
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 42-43
- https://doi.org/10.1039/c39840000042
Abstract
The compounds M1(CO)(PPh3)3(M1= Pt, Pd) react with M2Cl2(PhCN)2(M2= Pt, Pd) in tetrahydrofuran at room temperature to afford the new homo [M1= M2= Pt (1); M1= M2= Pd (2)] or hetero [M1= Pt, M2= Pd (3); M1= Pd, M2= Pt(4)] bimetallic complexes M1M2Cl2(µ-CO)(PPh3)3via formal oxidative-addition of the M2(II)–Cl bond at the M1(0) centre; complex (1) has been structurally characterized by X-ray diffraction.Keywords
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