DIALKYL PHOSPHOROISOTHIOCYANATIDATES
- 1 March 1959
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 37 (3) , 525-528
- https://doi.org/10.1139/v59-072
Abstract
An improved method for the preparation of dialkyl phosphoroisothiocyanatidates (II) is given. These compounds (II) are labile and decompose under the influence of heat and catalysts to the corresponding alkyl thiocyanates (III). In the presence of water they hydrolyze to dialkyl hydrogenphosphates (VI) in high yield. A series of thiourea derivatives (VII) has been prepared from II and amines.Keywords
This publication has 3 references indexed in Scilit:
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- The Preparation of Tetraethyl Pyrophosphate and Other Tetraalkyl PyrophosphatesJournal of the American Chemical Society, 1948
- PRODUCTION OF IMIDO THIOL ESTERS BY THE CONDENSATION OF THIOCYANATES WITH RESORCINOL OR PHLOROGLUCINOLJournal of the American Chemical Society, 1923