Absolute configuration and biosynthesis of tiliacorine and tiliacornine
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 226b-228
- https://doi.org/10.1039/c3978000226b
Abstract
Biosynthetic experiments with (R)- and (S)-N methylcoclaurines in Tiliacoraracemosa Colebr. established that tiliacorine has the (S) and (R) configuration at the asymmetric centres C(1) and C(1′), respectively, and tiliacorinine has the (SS) configuration at both asymmetric centres.Keywords
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