Brillouin-scattering study of the ferroelastic transition in KH3(SeO3)2 and KD3(SeO3)2 under uniaxial stress

Abstract
The c55 elastic constant of KH3 (SeO3)2 and KD3 (SeO3)2 has been investigated by Brillouin scattering in the vicinity of the ferroelastic transition in free crystal and under applied uniaxial stress. At zero stress, c55 exhibits remarkable softening at the transition with no departure from classical linear temperature dependence. The effect of the σ5 stress component can be very well described by a Landau-type free-energy model. On deuteration, only the temperature, at which the protons or deuterons would order without coupling to the strain, is increased; the other parameters in the free energy are not essentially affected.