Photolysis of Aromatic Oxime Esters. Finding of Aromatic Substitution by Diphenylmethyleneimino Radicals
- 1 August 1975
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 48 (8) , 2393-2394
- https://doi.org/10.1246/bcsj.48.2393
Abstract
Diphenylmethyleneimino radicals, Ph2C=N·, generated from photolysis of benzophenoxime benzoates undergo aromatic substitution on benzene as well as dimerization into azine. On the other hand, phenylmethyleneimino radicals, PhCH=N·, generated from photolysis of benzaldoxime benzoate are oxidized to benzonitrile in preference to dimerization.Keywords
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