Platinum-195 and phoshorus-31 nuclear magnetic resonance studies of some platinum hydrides

1 January 1968

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 3047-3050
https://doi.org/10.1039/j19680003047

Abstract

The ¹⁹⁵Pt and ³¹P chemical shifts and the platinum–phosphorus coupling constants have been determined for some platinum hydrides trans-[Pt(PEt₃)₂HL] where L is a series of anionic ligands. The platinum chemical shifts are interpreted in terms of the variation of the paramagnetic shielding term which arises from changes in the σ- and π-covalency of the metal–ligand (L) bond.

Keywords

NUCLEAR MAGNETIC RESONANCE