Spectre de rotation, couplage quadripolaire et structure du bromure de vinyle
- 1 January 1963
- journal article
- Published by EDP Sciences in Journal de Physique et le Radium
- Vol. 24 (8) , 633-637
- https://doi.org/10.1051/jphys:01963002408063300
Abstract
Les spectres de rotation pure de 22 espèces isotopiques du bromure de vinyle ont été étudiés entre 13 et 25 Gcs. Huit transitions du type a R0.1 ont été observées entre les niveaux de J = 1 à J = 3. Les dimensions suivantes ont pu être calculées par la méthode de Kraitchman : [FORMULE] Le couplage quadripolaire présente une asymétrie η = — 0,08 autour de l'axe de la liaison C — BrKeywords
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