Reaction of (C5Me5)2Yb with fluorocarbons: formation of (C5Me5)4Yb2(µ-F) by intermolecular C–F activation
- 1 January 1989
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 136-137
- https://doi.org/10.1039/c39890000136
Abstract
Addition of C6F6 and other fluoroaromatics and fluoroalkenes, though not C2F6 or CF3 CH3, to (C5Me5)2 Yb gives the mixed-valence complex (C5Me5)4Yb2(µ-F) with a linear, asymmetric YbII–F–YbIII bond.Keywords
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