Enthalpies of formation of 1 : 1,1 : 2, and 2 : 1 adducts of xenon difluoride with antimony, niobium, and tantalum pentafluorides
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 16,p. 1740-1742
- https://doi.org/10.1039/dt9740001740
Abstract
Standard enthalpies of formation of XeF2,MF5, XeF2,2MF5(M = Sb, Ta, or Nb), and 2XeF2,M F5(M = Sb or Ta) have been estimated from their heats of alkaline hydrolyses. The ionicity order of these compounds (Sb > Ta > Nb) adduced from vibrational spectroscopy is confirmed by the thermochemical results.Keywords
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