Spectroscopic studies of inorganic fluoro-complexes. Part III. Fluorine-19 nuclear magnetic resonance studies of silicon(IV), germanium(IV), and titanium(IV) fluoro-complexes

1 January 1970

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 2569-2574
https://doi.org/10.1039/j19700002569

Abstract

Anions of the type MF_6–2x B_x ^2–(M = Si^IV, Ge^IV, or Ti^IV; B = bidentate-ligand) have been characterised in solution by ¹⁹F n.m.r. spectroscopy. For Ge^IV and Ti^IV, anions of the type MF₅OR^2– and MF₅O₂CR^2– have also been observed. Redistribution reactions of M(ox)₃ ^2– and MF₆ ^2– have been studied quantitatively (M = Si^IV, Ge^IV, Sn^IV, and Ti^IV).

Keywords

NUCLEAR MAGNETIC RESONANCE
TITANIUM

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