HIGHLY STEREOSELECTIVE SYNTHESIS OF α-d-GLUCOPYRANOSIDES BY THE N-IODOSUCCINIMIDE-PROMOTED INTERNAL CYCLIZATION

Abstract
Highly stereoselective cyclizations of hydroxy enol ethers are effected by N-iodosuccinimide to result in the exclusive formation of 2′-deoxy-2′-iodo-α-D-glucopyranosides. An analog of glycolipid is also successfully synthesized according to the present method.

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