Chemical Reactivity of PF[sub 5] and LiPF[sub 6] in Ethylene Carbonate/Dimethyl Carbonate Solutions
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- 1 January 2001
- journal article
- Published by The Electrochemical Society in Electrochemical and Solid-State Letters
- Vol. 4 (4) , A42-A44
- https://doi.org/10.1149/1.1353158
Abstract
The thermal decomposition of in a mixture (1:1 molar ratio) of ethylene carbonate (EC)/dimethyl carbonate (DMC) at 85°C is compared to the reaction between EC/DMC and gas. Both produce a brown solution and gaseous products. The reaction products from and in 1:1 EC/DMC, detected by gas chromatography, are similar. Proton nuclear magnetic resonance provided evidence for the presence of oligoether carbonates in the reaction products. © 2001 The Electrochemical Society. All rights reserved.Keywords
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