Fully reversible carbon protonation in the hydrolysis of keten selenoacetals
- 1 January 1981
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 738-739
- https://doi.org/10.1039/c39810000738
Abstract
Kinetic solvent isotope effect [k(H3O+)/k(D3O+)ca. 100%) during acidic hydrolysis of keten selenoacetals establish that these reactions proceed through a pre-equilibrium carbon protonation step.Keywords
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