DYNAMIC STEREOCHEMISTRY OF SYMMETRICALLY BUT DIFFERENTLY SUBSTITUTED DIPHOSPHANES
- 1 May 1986
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 27 (1-2) , 55-64
- https://doi.org/10.1080/03086648608072758
Abstract
The main interest of our work in Bonn during the last years was in the field of phosphorus-carbon compounds with multiple bonds. Beside the synthesis of new classes of compounds we were particularly interested in the amazing analogy between the PC- and the CC-double bond, which could be proved by evidence of E/Z isomers and a clear indication of pericyclic reactions.Keywords
This publication has 2 references indexed in Scilit:
- Proton and phosphorus-31 nuclear magnetic resonance evidence for the existence of 1,2-diphenyldiphosphine in equilibrium with phenylphosphine and pentaphenylcyclopentaphosphineJournal of the American Chemical Society, 1972
- The stereochemical lability of diphosphines and diarsinesJournal of the American Chemical Society, 1968