Photochemistry of [(η5-C5Me5)Re(CO)3] in benzene solution structure of [{(η5-C5Me5)Re(CO)2}2(µ-η2,η2′-C6H6)
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1576-1578
- https://doi.org/10.1039/c39850001576
Abstract
U.v irradiation of {(η5C5Me5)Re(CO)3] in benzene yields the stable complex [{(η-5C5Me5)Re(CO)2}2(µ-η2,η2′-C6H6)]; X-ray diffraction reveals a pronounced double-bond localization in the double co-ordinated benzene ligand.Keywords
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