Activation of molecular oxygen, hydrogen, carbon monoxide, and olefins by a ruthenium(II) complex
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 11,p. 561
- https://doi.org/10.1039/c29710000561
Abstract
Dichlorotris(triphenylarsine)ruthenium(II), dissolved in benzene, readily activates molecular O2, H2, CO, and olefins to give new catalytic species of importance in homogeneous catalysis; the oxygen complex is the first known example of a 1 : 1 paramagentic complex of a d6 metal ion.Keywords
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