13C nuclear magnetic resonance spectra. Part 9. Strain effects on 13C chemical shifts of triamantane
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 3,p. 357-359
- https://doi.org/10.1039/p29790000357
Abstract
The 13C n.m.r. spectrum of triamantane (3) observed at 22.64 and 62.8 MHz is assigned using selective 1H decoupling. Internal strain causing geometrical distortions at the quaternary carbon leads to a non-additive down-field shift of its signal.Keywords
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