Yb 3d CORE-LEVEL PHOTOEMISSION OF YbN, YbP AND YbAs

Abstract
We present an experimental and theoretical study of the 3d core level spectra along the pnicitides YbN, YbP and YbAs and determine the degree of valence mixing as a function of anion electronegativity. The experimental spectra are obtained using SiKα radiation (hν = 1740 eV). They show on the low binding energy side of the dominating 3d9 4f13 multiplets a weak 3d9 4f14 doublet. The theoretical lineshapes and satellite structures are obtained from a combination of many body techniques due to Gunnarsson and Schoenhammer [1] and standard atomic calculations in intermediate coupling

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