Enantioselective catalysis using phosphorus-donor ligands containing two or three P–N or P–O bonds
- 26 July 2002
- journal article
- review article
- Published by Royal Society of Chemistry (RSC) in Chemical Society Reviews
- Vol. 31 (5) , 259-268
- https://doi.org/10.1039/b200392a
Abstract
This review describes some recent developments in the area of asymmetric catalysis using organometallic complexes of ligands which contain two or three P–O or P–N bonds. This category of ligands has, until the last five years or so, been underrepresented in asymmetric catalysis, particularly in contrast to phosphine ligands. Recent breakthroughs in methodology for the synthesis and manipulation of such materials have resulted in the delivery of ligands which demonstrate remarkably high enantioinduction properties in a series of asymmetric transformations.Keywords
This publication has 71 references indexed in Scilit:
- Rhodium-Mediated Asymmetric Hydroformylation with a Novel Bis(diazaphospholidine) LigandPublished by Wiley ,2000
- Highly Enantioselective Rh-Catalyzed Hydrogenation Reactions Based on Chiral Monophosphite LigandsPublished by Wiley ,2000
- A Practical Method for the Large-Scale Synthesis of Diastereomerically Pure (2R,5S)- 3-Phenyl-2-(8-quinolinoxy)- 1,3-diaza-2-phosphabicyclo-[3.3.0]-octane Ligand (QUIPHOS). Synthesis and X-ray Structure of Its Corresponding Chiral π-Allyl Palladium ComplexThe Journal of Organic Chemistry, 1999
- Catalytic Enantioselective Hydrosilylation of Ketones with Rhodium-Phosphite Complexes Containing a TADDOLate and a Dihydrooxazole UnitHelvetica Chimica Acta, 1999
- Catalytic Enantioselective Annulations via 1,4-Addition−Aldol Cyclization of Functionalized Organozinc ReagentsJournal of the American Chemical Society, 1999
- New Diphosphite Ligands for Catalytic Asymmetric Hydrogenation: The Crucial Role of Conformationally Enantiomeric DiolsAngewandte Chemie International Edition in English, 1999
- Enantioselective allylic substitution catalyzed by an iridium complex: remarkable effects of the counter cationChemical Communications, 1999
- Enantioselective Copper-Catalyzed 1,4-Addition of Organozinc Reagents to Enones Using Chiral Oxazoline-Phosphite LigandsSynlett, 1997
- Mechanistic Aspects of the Alternating Copolymerization of Propene with Carbon Monoxide Catalyzed by Pd(II) Complexes of Unsymmetrical Phosphine−Phosphite LigandsJournal of the American Chemical Society, 1997
- Asymmetric Hydroformylation of Heterocyclic Olefins Catalyzed by Chiral Phosphine−Phosphite−Rh(I) ComplexesThe Journal of Organic Chemistry, 1997