NEW SYNTHETIC ROUTE TO DIALKYLPHOSPHINIC ACIDS
- 4 October 1989
- journal article
- research article
- Published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements
- Vol. 45 (3-4) , 151-154
- https://doi.org/10.1080/10426508908045011
Abstract
The dialkylphosphinic acids, 5a-5e, can be obtained by reacting bis(trimethylsiloxy)phosphine with the highly reactive alkyl halides, 2a-2e, in the presence of chlorotrimethylsilane and triethylamine, followed by ethanolysis of the resulting trimethylsilyl dialkylphosphinates, 4a-4e.Keywords
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