1,3,4-Thiadiazole-2,5-dithiol as a complexing agent. Complexes of RuIII, RuII, RhIII, PdIV IrIII and PtIV
- 1 January 1975
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 28 (4) , 763-771
- https://doi.org/10.1071/ch9750763
Abstract
Complexes of RuIII, RuII, RhIII, PdIV, IrIII and PtIV with 1,3,4-thiadiazole- 2,5-dithiol have been prepared. Probable structures for the complexes have been proposed on the basis of chemical analyses, magnetic susceptibility and electronic and infrared spectral data. Crystal field parameters have been calculated which are in accordance with the structures proposed. In every complex the ligand behaves as a unidentate towards two metal ions.Keywords
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