Radical translocation reactions across amides. 1,5-Hydrogen-transfer reactions of o-iodobenzamides and N-(o-iodobenzyl) amides
- 1 January 1994
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 11,p. 1377-1393
- https://doi.org/10.1039/p19940001377
Abstract
Radicals derived from N,N-disubstituted o-iodobenzamides undergo rapid 1,5-hydrogen-transfer reactions. The regioselectivity of these reactions is coupled to the rotamer population of the starting iodobenzamide, and the products vary with changing amide substituents. Related 1,5-hydrogen-transfer reactions are observed for N-alkyl-N-(o-iodobenzyl)-benzamides and -acetamides.Keywords
This publication has 0 references indexed in Scilit: