Molecular Reorientational Motion of the Benzene Molecule in a Mixture of Benzene with Carbon Tetrachloride by Raman Band Spape Analysis
- 1 October 1975
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 48 (10) , 2779-2781
- https://doi.org/10.1246/bcsj.48.2779
Abstract
The reorientational correlation times of the benzene molecule in mixtures of benzene with carbon tetrachloride were measured by the method of the Raman line shape analysis. The reorientational relaxation times τor of C6H6 in solutions increased with increasing mole fraction of CCl4. Information was also obtained on an intermolecular vibration-vibration energy transfer process which primarily affects the mean life time of the first excited vibrational state ν2 (a1g) in benzene in solutions.Keywords
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