Selenium tetrafluoride adducts. II. Adducts with boron trifluoride and some pentafluorides
- 15 February 1970
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 48 (4) , 657-663
- https://doi.org/10.1139/v70-106
Abstract
Adducts of selenium tetrafluoride with SbF5, AsF5, NbF5, TaF5, and BF3 have been investigated by means of infrared, Raman, and nuclear magnetic resonance spectroscopy and conductimetric and cryoscopic measurements. It is concluded that in the solid state these compounds are best formulated as having ionic structures SeF3+MF6−(BF4−), although the ions interact rather strongly by fluorine bridging. This fluorine bridging apparently persists in the molten state and to some extent in solution in nitrobenzene.Keywords
This publication has 0 references indexed in Scilit: