S NAr displacement of fluorine from pentafluoropyridin by sodium oximates: unprecedented substitution patterns

Abstract
Displacement of fluorine from pentafluoropyridine under conditions by sodium oximates RR′CNONa+[R,R′= Me or Ph; R = Me, R′= Ph (anti isomer)] suspended in benzene or diethyl ether yields O-tetrafluoropyridyl oximes arising from monosubstitution at both 2- and 4-positions.

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