Electrically Induced Perturbations of Halogen Nuclear Quadrupole Interactions in Polycrystalline Compounds. II. Microscopic Theory
- 15 September 1964
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 41 (6) , 1739-1747
- https://doi.org/10.1063/1.1726153
Abstract
The physical origins of electrically induced perturbations of quadrupole couplings in molecular solids are considered. Experiment and elementary theory are compared and it is concluded that polarizations of bonding electrons near the resonant nuclei are of dominant importance in determining the magnitudes of the electrically induced shifts.Keywords
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